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Reactions, Vol. 5, Pages 305-317: Generalized Linear Driving Force Formulas for Diffusion and Reaction in Porous Catalysts
Reactions doi: 10.3390/reactions5020015
Authors: Mirosław K. Szukiewicz Elżbieta Chmiel-Szukiewicz
Approximate models are a fast and most often precise tool for determining the effectiveness factor for heterogeneous catalysis processes that are realized in the real world. They are also frequently applied as robust transient models describing the work of a single catalyst pellet or as a part of a more complex model, for example, a reactor model, where mass balances for the gas phase and solid phase are necessary. So far, approximate models for diffusion and reaction processes have been presented for processes described by a single balance equation. In the present work, approximate models without the mentioned limitation are presented and discussed. In addition, simple rules are shown for the development of other complex approximate models without tedious derivation in the complex domain. The formulas considered in this work are typical long-time approximations of the transient process. The accuracy is good, especially in the range of small and intermediate Thiele modulus values.
